Catalytic reductive aldol and mannich reactions of enone, acrylate, and vinyl heteroaromatic pronucleophiles CC Meyer, E Ortiz, MJ Krische Chemical reviews 120 (8), 3721-3748, 2020 | 68 | 2020 |
Enantioselective Ruthenium-BINAP-Catalyzed Carbonyl Reductive Coupling of Alkoxyallenes: Convergent Construction of syn-sec,tert-Diols via (Z)-σ-Allylmetal … M Xiang, DE Pfaffinger, E Ortiz, GA Brito, MJ Krische Journal of the American Chemical Society 143 (23), 8849-8854, 2021 | 33 | 2021 |
Enantioselective metal-catalyzed reductive coupling of alkynes with carbonyl compounds and imines: convergent construction of allylic alcohols and amines E Ortiz, J Shezaf, YH Chang, MJ Krische ACS catalysis 12 (14), 8164-8174, 2022 | 27 | 2022 |
Understanding Halide Counterion Effects in Enantioselective Ruthenium-Catalyzed Carbonyl (α-Aryl) allylation: Alkynes as Latent Allenes and Trifluoroethanol-Enhanced Turnover … E Ortiz, JZ Shezaf, YH Chang, TP Gonçalves, KW Huang, MJ Krische Journal of the American Chemical Society 143 (40), 16709-16717, 2021 | 21 | 2021 |
Stereo-and Site-Selective Conversion of Primary Alcohols to Allylic Alcohols via Ruthenium-Catalyzed Hydrogen Auto-Transfer Mediated by 2-Butyne E Ortiz, YH Chang, JZ Shezaf, W Shen, MJ Krische Journal of the American Chemical Society 144 (19), 8861-8869, 2022 | 17 | 2022 |
Stereo‐and Site‐Selective Crotylation of Alcohol Proelectrophiles via Ruthenium‐Catalyzed Hydrogen Auto‐Transfer Mediated by Methylallene and Butadiene E Ortiz, BJ Spinello, Y Cho, J Wu, MJ Krische Angewandte Chemie 134 (49), e202212814, 2022 | 16 | 2022 |
Historical perspective on ruthenium-catalyzed hydrogen transfer and survey of enantioselective hydrogen auto-transfer processes for the conversion of lower alcohols to higher … E Ortiz, JZ Shezaf, W Shen, MJ Krische Chemical Science 13 (43), 12625-12633, 2022 | 14 | 2022 |
A Metal-Free Reductive N-Alkylation of Indoles with Aldehydes NA Clanton, TE Spiller, E Ortiz, Z Gao, JM Rodriguez-Poirier, ... Organic Letters 23 (9), 3233-3236, 2021 | 11 | 2021 |
Palladium(I)-Iodide-Catalyzed Deoxygenative Heck Reaction of Vinyl Triflates: A Formate-Mediated Cross-Electrophile Reductive Coupling with cine-Substitution YH Chang, W Shen, JZ Shezaf, E Ortiz, MJ Krische Journal of the American Chemical Society 145 (42), 22890-22895, 2023 | 7 | 2023 |
Carbonyl Allylation and Crotylation: Historical Perspective, Relevance to Polyketide Synthesis, and Evolution of Enantioselective Ruthenium-Catalyzed Hydrogen Auto-Transfer … E Ortiz, C Saludares, J Wu, Y Cho, CG Santana, MJ Krische Synthesis 55 (10), 1487-1496, 2023 | 7 | 2023 |
Asymmetric Ruthenium-Catalyzed Carbonyl Allylations by Gaseous Allene via Hydrogen Auto-Transfer: 1 versus 2 Alcohol Dehydrogenation for Streamlined Polyketide Construction C Saludares, E Ortiz, CG Santana, BJ Spinello, MJ Krische ACS catalysis 13 (3), 1662-1668, 2023 | 7 | 2023 |
Ruthenium‐Catalyzed C− C Coupling of Terminal Alkynes with Primary Alcohols or Aldehydes: α, β‐Acetylenic Ketones (Ynones) via Oxidative Alkynylation E Ortiz, MM Evarts, ZH Strong, JZ Shezaf, MJ Krische Angewandte Chemie 135 (23), e202303345, 2023 | 6 | 2023 |
Site-Selective Functionalization of Unactivated Allylic C–H Bonds via Direct Deprotonation with KTMP: Application to the Formal Total Synthesis of (+)-Artemisinin from Amorphadiene NA Clanton, NA Wilson, E Ortiz, ST Blumberg, DE Frantz Organic Letters 25 (1), 277-281, 2023 | 5 | 2023 |
Intermolecular Metal-Catalyzed C–C Coupling of Unactivated Alcohols or Aldehydes for Convergent Ketone Construction beyond Premetalated Reagents BJ Spinello, ZH Strong, E Ortiz, MM Evarts, MJ Krische ACS catalysis 13 (16), 10976-10987, 2023 | 3 | 2023 |
Leveraging the Stereochemical Complexity of Octahedral Diastereomeric-at-Metal Catalysts to Unlock Regio-, Diastereo-, and Enantioselectivity in Alcohol-Mediated C–C Couplings … JZ Shezaf, CG Santana, E Ortiz, CC Meyer, P Liu, K Sakata, KW Huang, ... Journal of the American Chemical Society 146 (12), 7905-7914, 2024 | 1 | 2024 |
CCDC 2099746: Experimental Crystal Structure Determination: 3-(bicyclo [4.2. 0] octa-1, 3, 5-trien-3-yl) pent-4-en-2-yl 3, 5-dinitrobenzoate E Ortiz, JZ Shezaf, YH Chang, T Goncalves, KW Huang, MJ Krische Cambridge Crystallographic Data Centre, 2021 | | 2021 |
CCDC 2099745: Experimental Crystal Structure Determination:(1-[1-(di-t-butylphosphanyl) ethyl]-2-(dicyclohexylphosphanyl) ferrocene)-allyl-carbonyl-chloro-ruthenium E Ortiz, JZ Shezaf, YH Chang, T Goncalves, KW Huang, MJ Krische Cambridge Crystallographic Data Centre, 2021 | | 2021 |