A Gold Catalyst for Carbene‐Transfer Reactions from Ethyl Diazoacetate MR Fructos, TR Belderrain, P de Frémont, NM Scott, SP Nolan, ... Angewandte Chemie 117 (33), 5418-5422, 2005 | 486 | 2005 |
Reactivity of Ru(H)(H2)Cl(PCy3)2 with Propargyl and Vinyl Chlorides: New Methodology To Give Metathesis-Active Ruthenium Carbenes TE Wilhelm, TR Belderrain, SN Brown, RH Grubbs Organometallics 16 (18), 3867-3869, 1997 | 212 | 1997 |
Reaction between Ruthenium (0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts TR Belderrain, RH Grubbs Organometallics 16 (18), 4001-4003, 1997 | 188 | 1997 |
Cyclohexane and Benzene Amination by Catalytic Nitrene Insertion into C−H Bonds with the Copper-Homoscorpionate Catalyst TpBr3Cu(NCMe) MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, PJ Pérez Journal of the American Chemical Society 125 (40), 12078-12079, 2003 | 171 | 2003 |
Intermolecular copper-catalyzed carbon− hydrogen bond activation via carbene insertion MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, PJ Pérez Journal of the American Chemical Society 124 (6), 896-897, 2002 | 164 | 2002 |
Complete Control of the Chemoselectivity in Catalytic Carbene Transfer Reactions from Ethyl Diazoacetate: An N-Heterocyclic Carbene−Cu System That … MR Fructos, TR Belderrain, MC Nicasio, SP Nolan, H Kaur, ... Journal of the American Chemical Society 126 (35), 10846-10847, 2004 | 152 | 2004 |
Highly Regioselective Functionalization of Aliphatic Carbon− Hydrogen Bonds with a Perbromohomoscorpionate Copper (I) Catalyst A Caballero, MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, ... Journal of the American Chemical Society 125 (6), 1446-1447, 2003 | 146 | 2003 |
P. d. Fremont, NM Scott, SP Nolan, MM DıazRequejo and PJ Pérez MR Fructos, TR Belderrain Angew. Chem., Int. Ed 44, 5284-5288, 2005 | 116 | 2005 |
Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium ZD Miller, W Li, TR Belderrain, J Montgomery Journal of the American Chemical Society 135 (41), 15282-15285, 2013 | 115 | 2013 |
Functionalization of primary carbon− hydrogen bonds of alkanes by carbene insertion with a silver-based catalyst J Urbano, TR Belderraín, MC Nicasio, S Trofimenko, MM Díaz-Requejo, ... Organometallics 24 (7), 1528-1532, 2005 | 114 | 2005 |
Copper-homoscorpionate complexes as very active catalysts for the olefin aziridination reaction MA Mairena, MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, ... Organometallics 23 (2), 253-256, 2004 | 112 | 2004 |
Copper (I)− Homoscorpionate Catalysts for the Preferential, Kinetically Controlled Cis Cyclopropanation of α-Olefins with Ethyl Diazoacetate MM Díaz-Requejo, A Caballero, TR Belderraín, MC Nicasio, S Trofimenko, ... Journal of the American Chemical Society 124 (6), 978-983, 2002 | 111 | 2002 |
A series of ruthenium (II) ester-carbene complexes as olefin metathesis initiators: metathesis of acrylates M Ulman, TR Belderrain, RH Grubbs Tetrahedron Letters 41 (24), 4689-4693, 2000 | 106 | 2000 |
Synthesis, Structural Characterization, and Catalytic Activity of IPrNi(styrene)2 in the Amination of Aryl Tosylates MJ Iglesias, JF Blandez, MR Fructos, A Prieto, E Alvarez, TR Belderrain, ... Organometallics 31 (17), 6312-6316, 2012 | 86 | 2012 |
Functionalization of Carbon− Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper (I)− Homoscorpionate Catalysts A Caballero, MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, ... Organometallics 22 (20), 4145-4150, 2003 | 84 | 2003 |
Catalytic dehalogenation of aryl chlorides mediated by ruthenium (II) phosphine complexes ME Cucullu, SP Nolan, TR Belderrain, RH Grubbs Organometallics 18 (7), 1299-1304, 1999 | 83 | 1999 |
Atom transfer radical reactions as a tool for olefin functionalization–on the way to practical applications JM Muñoz‐Molina, TR Belderrain, PJ Pérez European Journal of Inorganic Chemistry 2011 (21), 3155-3164, 2011 | 79 | 2011 |
Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp= Dihydridobis (1-pyrazolyl) borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated … MM Díaz-Requejo, TR Belderrain, MC Nicasio, F Prieto, PJ Pérez Organometallics 18 (14), 2601-2609, 1999 | 78 | 1999 |
Unprecedented Highly cis-Diastereoselective Olefin Cyclopropanation Using Copper Homoscorpionate Catalysts MM Díaz-Requejo, TR Belderraín, S Trofimenko, PJ Pérez Journal of the American Chemical Society 123 (13), 3167-3168, 2001 | 76 | 2001 |
Reaction of Ethyl Diazoacetate with Alkyl-Aromatic Substrates: Influence of the TpxCu Catalyst in the Addition versus Insertion Chemoselectivity (Tpx= Homoscorpionate) ME Morilla, MM Díaz-Requejo, TR Belderrain, MC Nicasio, S Trofimenko, ... Organometallics 23 (2), 293-295, 2004 | 72 | 2004 |