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Robert J. Gilliard, Jr.
Robert J. Gilliard, Jr.
Novartis Professor of Chemistry
Verified email at mit.edu - Homepage
Title
Cited by
Cited by
Year
Carbene-stabilized parent phosphinidene
Y Wang, Y Xie, MY Abraham, RJ Gilliard Jr, P Wei, HF Schaefer III, ...
Organometallics 29 (21), 4778-4780, 2010
1572010
Oxidation of carbene-stabilized diarsenic: diarsene dications and diarsenic radical cations
MY Abraham, Y Wang, Y Xie, RJ Gilliard Jr, P Wei, BJ Vaccaro, ...
Journal of the American Chemical Society 135 (7), 2486-2488, 2013
1072013
A stable, crystalline beryllium radical cation
G Wang, JE Walley, DA Dickie, S Pan, G Frenking, RJ Gilliard Jr
Journal of the American Chemical Society 142 (10), 4560-4564, 2020
772020
N-Heterocyclic olefin stabilized borenium cations
Y Wang, MY Abraham, RJ Gilliard Jr, DR Sexton, P Wei, GH Robinson
Organometallics 32 (22), 6639-6642, 2013
742013
Carbene-stabilized beryllium borohydride
RJ Gilliard Jr, MY Abraham, Y Wang, P Wei, Y Xie, B Quillian, ...
Journal of the American Chemical Society 134 (24), 9953-9955, 2012
742012
Isolation of cyclic (alkyl)(amino) carbene–bismuthinidene mediated by a beryllium (0) complex
G Wang, LA Freeman, DA Dickie, R Mokrai, Z Benkő, RJ Gilliard Jr
Chemistry–A European Journal 25 (17), 4335-4339, 2019
722019
Persistent borafluorene radicals
W Yang, KE Krantz, LA Freeman, DA Dickie, A Molino, G Frenking, S Pan, ...
Angewandte Chemie International Edition 59 (10), 3850-3854, 2020
692020
NHC‐Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes
Y Wang, Y Xie, MY Abraham, RJ Gilliard, P Wei, CF Campana, ...
Angewandte Chemie International Edition 40 (51), 10173-10176, 2012
652012
From anionic N-heterocyclic dicarbenes to abnormal carbene–borane complexes: a logical synthetic route
Y Wang, MY Abraham, RJ Gilliard Jr, P Wei, JC Smith, GH Robinson
Organometallics 31 (3), 791-793, 2012
572012
Crystalline BP‐Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene
W Yang, KE Krantz, DA Dickie, A Molino, DJD Wilson, RJ Gilliard Jr
Angewandte Chemie International Edition 59 (10), 3971-3975, 2020
472020
Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions
W Yang, KE Krantz, LA Freeman, DA Dickie, A Molino, A Kaur, ...
Chemistry–A European Journal 25 (54), 12512-12516, 2019
462019
From the parent phosphinidene–carbene adduct NHC [double bond, length as m-dash] PH to cationic P 4-rings and P 2-cycloaddition products
A Beil, RJ Gilliard, H Grützmacher
Dalton Transactions 45 (5), 2044-2052, 2016
422016
Carbodicarbene bismaalkene cations: unravelling the complexities of carbene versus carbone in heavy pnictogen chemistry
JE Walley, LS Warring, G Wang, DA Dickie, S Pan, G Frenking, ...
Angewandte Chemie 133 (12), 6756-6764, 2021
402021
s-Block carbodicarbene chemistry: C (sp 3)–H activation and cyclization mediated by a beryllium center
JE Walley, G Breiner, G Wang, DA Dickie, A Molino, JL Dutton, ...
Chemical communications 55 (13), 1967-1970, 2019
392019
Synthesis and molecular structure of an abnormal carbene–gallium chloride complex
M Chen, Y Wang, RJ Gilliard, P Wei, NA Schwartz, GH Robinson
Dalton Transactions 43 (38), 14211-14214, 2014
312014
Synthesis and reactivity of low-oxidation-state alkaline earth metal complexes
LA Freeman, JE Walley, RJ Gilliard Jr
Nature Synthesis 1 (6), 439-448, 2022
272022
s‐Block multiple bonds: isolation of a beryllium imido complex
G Wang, JE Walley, DA Dickie, A Molino, DJD Wilson, RJ Gilliard Jr
Angewandte Chemie International Edition 60 (17), 9407-9411, 2021
272021
Stepwise reduction at magnesium and beryllium: cooperative effects of carbenes with redox non-innocent α-diimines
LA Freeman, JE Walley, AD Obi, G Wang, DA Dickie, A Molino, ...
Inorganic Chemistry 58 (16), 10554-10568, 2019
272019
Dynamic Complexation of Copper (I) Chloride by Carbene‐Stabilized Disilicon
M Chen, Y Wang, Y Xie, P Wei, RJ Gilliard Jr, NA Schwartz, ...
Chemistry–A European Journal 20 (30), 9208-9211, 2014
272014
Chromophore-derivatized semifluorinated polymers for colorimetric and turn-on fluorescent anion detection
RJ Gilliard Jr, ST Iacono, SM Budy, JD Moody, DW Smith Jr, RC Smith
Sensors and Actuators B: Chemical 143 (1), 1-5, 2009
272009
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