| Role of (1,3) {Cu-Cu} Interaction on the Magneto-Caloric Effect of Trinuclear {CuII-GdIII-CuII} Complexes: Combined DFT and Experimental Studies MK Singh, T Rajeshkumar, R Kumar, SK Singh, G Rajaraman Inorganic chemistry 57 (4), 1846-1858, 2018 | 37 | 2018 |
| Role of oxidation state, ferryl-oxygen, and ligand architecture on the reactivity of popular high-valent FeIV= O species: A theoretical perspective R Kumar, B Pandey, A Sen, M Ansari, S Sharma, G Rajaraman Coordination Chemistry Reviews 419, 213397, 2020 | 32 | 2020 |
| Axial vs. Equatorial Ligand Rivalry in Controlling the Reactivity of Iron (IV)‐Oxo Species: Single‐State vs. Two‐State Reactivity R Kumar, A Ansari, G Rajaraman Chemistry–A European Journal 24 (26), 6818-6827, 2018 | 31 | 2018 |
| Stepwise Reversible Oxidation of N-Peralkyl-Substituted NHC–CAAC Derived Triazaalkenes: Isolation of Radical Cations and Dications D Mandal, R Dolai, N Chrysochos, P Kalita, R Kumar, D Dhara, A Maiti, ... Organic letters 19 (20), 5605-5608, 2017 | 31 | 2017 |
| Molecular Memory Switching Device Based on a Tetranuclear Organotin Sulfide Cage [(RSnIV)4(μ-S)6]·2CHCl3·4H2O (R = 2-(Phenylazo)phenyl): Synthesis … A Mishra, A Betal, N Pal, R Kumar, P Lama, S Sahu, RK Metre ACS Applied Electronic Materials 2 (1), 220-229, 2019 | 20 | 2019 |
| Influence of N-Substitution on the Formation and Oxidation of NHC–CAAC-Derived Triazaalkenes D Mandal, R Dolai, R Kumar, S Suhr, N Chrysochos, P Kalita, ... The Journal of Organic Chemistry 84 (14), 8899-8909, 2019 | 18 | 2019 |
| Computational insight into the hydroamination of an activated olefin, as catalyzed by a 1, 2, 4-triazole-derived nickel (II) N-heterocyclic carbene complex R Kumar, M Katari, A Choudhary, G Rajaraman, P Ghosh Inorganic Chemistry 56 (24), 14859-14869, 2017 | 14 | 2017 |
| Hemi labile intramolecular N→ Sn coordination in a diorganotin (IV) sulfide [R2Sn (µ-S)] 2 (R= 2-phenylazophenyl) complex: synthesis, structure, DFT-NBO and antibacterial studies A Mishra, R Kumar, A Khandelwal, P Lama, M Chhabra, RK Metre Polyhedron 205, 115302, 2021 | 12 | 2021 |
| Dinuclear Monoorganostannoxane [(RSnIV)2(μ-OH)(μ-OCH3)Cl4]·CH3OH (R= 2-(Phenylazo)phenyl) Assembled Using Intramolecular Coordination Approach … A Mishra, A Betal, R Kumar, P Lama, S Sahu, RK Metre ACS Applied Electronic Materials 3 (1), 203-210, 2020 | 11 | 2020 |
| Assembly of Di-, tetra-and hexanuclear organostannoxanes using hemi labile intramolecular n→ sn coordination: synthesis, structure, DFT and antibacterial studies A Mishra, A Batar, R Kumar, A Khandelwal, P Lama, M Chhabra, ... Polyhedron 209, 115487, 2021 | 9 | 2021 |
| Comparative oxidative ability of iron (III)-iodosylarene vs. high-valent iron (IV/V)-oxo species: Is lower oxidation state a key to enhance selectivity in organic transformations R Kumar, B Pandey, G Rajaraman J. Indian Chem. Soc 96, 825-836, 2019 | 9 | 2019 |
| Octanuclear organotin copper sulfide cage [(RSnCu) 4 (μ3-S) 8]· 2CHCl3 (R= 2-phenylazophenyl) assembled using intramolecular coordination approach: synthesis, structure and DFT … A Mishra, R Kumar, P Lama, RK Metre Journal of Molecular Structure 1239, 130458, 2021 | 8 | 2021 |
| Mechanistic Insights into the Oxygen Atom Transfer Reactions by Nonheme Manganese Complex: A Computational Case Study on the Comparative Oxidative Ability of Manganese … R Kumar, B Pandey, A Singh, G Rajaraman Inorganic Chemistry 60 (16), 12085-12099, 2021 | 8 | 2021 |
| Design and Construction of Aroyl‐Hydrazone Derivatives: Synthesis, Crystal Structure, Molecular Docking and Their Biological Activities P Kumari, SN Ansari, R Kumar, AK Saini, SM Mobin Chemistry & Biodiversity 16 (11), e1900315, 2019 | 7 | 2019 |
| A six-coordinate high-spin Fe (IV) O species of cucurbit [5] uril: a highly potent catalyst for CH hydroxylation of methane, if synthesised R Kumar, M Sundararajan, G Rajaraman Chem. Commun. 57, 13760-13763, 2021 | 5* | 2021 |
| “Abnormal” Addition of NHC to a Conjugate Acid of CAAC: Formation of N‐Alkyl‐Substituted CAAC D Mandal, R Dolai, P Kalita, RS Narayanan, R Kumar, S Sobottka, ... Chemistry–A European Journal 24 (48), 12722-12727, 2018 | 5 | 2018 |
| The Fully Oxidized State of the Glutamate Coordinated O2-Tolerant [NiFe]-Hydrogenase Shows a Ni(III)/Fe(III) Open-Shell Singlet Ground State R Kumar, M Stein Journal of the American Chemical Society 145 (20), 10954-10959, 2023 | 4 | 2023 |
| A theoretical perspective on the reactivity of high-valent Mn-Oxo/nitrene species towards oxidative transformations A Sen, R Kumar, G Rajaraman Inorganica Chimica Acta 529, 120654, 2022 | 2 | 2022 |
| Unexpected formation of 2-methyl-1H-naphtho [2, 3-d] imidazole via decarboxylation governed mechanistic pathway ZA Siddiqui, S Lambud, A Bhadke, R Kumar, N Prajesh, N Sekar, S More Chemical Physics 565, 111735, 2023 | 1 | 2023 |
| Rebound or Cage Escape? The Role of the Rebound Barrier for the Reactivity of Non‐Heme High‐Valent FeIV=O Species R Kumar, A Ansari, P Comba, G Rajaraman Chemistry–A European Journal 30 (6), e202303300, 2024 | | 2024 |
Rajaraman GopalanIIT Bombay, Powai, Mumbai-400076Verified email at chem.iitb.ac.in
