Monofluorination of organic compounds: 10 years of innovation PA Champagne, J Desroches, JD Hamel, M Vandamme, JF Paquin Chemical reviews 115 (17), 9073-9174, 2015 | 858 | 2015 |
Friedel–Crafts Reaction of Benzyl Fluorides: Selective Activation of C F Bonds as Enabled by Hydrogen Bonding PA Champagne, Y Benhassine, J Desroches, JF Paquin Angewandte Chemie International Edition 53 (50), 13835-13839, 2014 | 226 | 2014 |
Organic fluorine as a hydrogen-bond acceptor: Recent examples and applications PA Champagne, J Desroches, JF Paquin Synthesis 47 (03), 306-322, 2015 | 183 | 2015 |
Enabling Nucleophilic Substitution Reactions of Activated Alkyl Fluorides through Hydrogen Bonding PA Champagne, J Pomarole, MÈ Thérien, Y Benhassine, S Beaulieu, ... Organic letters 15 (9), 2210-2213, 2013 | 105 | 2013 |
Stereocontrolled Approach to Bromofluoroalkenes and Their Use for the Synthesis of Tri-and Tetrasubstituted Fluoroalkenes G Landelle, PA Champagne, X Barbeau, JF Paquin Organic letters 11 (3), 681-684, 2009 | 65 | 2009 |
Origins of Selectivity and General Model for Chiral Phosphoric Acid-Catalyzed Oxetane Desymmetrizations PA Champagne, KN Houk Journal of the American Chemical Society 138 (38), 12356-12359, 2016 | 54 | 2016 |
Synthesis of [18F] Fluoroarenes by Nucleophilic Radiofluorination of N‐Arylsydnones MK Narayanam, G Ma, PA Champagne, KN Houk, JM Murphy Angewandte Chemie International Edition 56 (42), 13006-13010, 2017 | 50 | 2017 |
Activation Mode and Origin of Selectivity in Chiral Phosphoric Acid-Catalyzed Oxacycle Formation by Intramolecular Oxetane Desymmetrizations R Maji, PA Champagne, KN Houk, SE Wheeler ACS Catalysis 7 (10), 7332-7339, 2017 | 48 | 2017 |
Recent advances in the stereoselective synthesis of acyclic all-carbon tetrasubstituted alkenes F Buttard, J Sharma, PA Champagne Chemical Communications 57, 4071-4088, 2021 | 47 | 2021 |
Sydnone-Based Approach to Heterohelicenes through 1, 3-Dipolar-Cycloadditions E Yen-Pon, PA Champagne, L Plougastel, S Gabillet, P Thuéry, ... Journal of the American Chemical Society 141 (4), 1435-1440, 2019 | 47 | 2019 |
Bioorthogonal release of sulfonamides and mutually orthogonal liberation of two drugs Z Shao, W Liu, H Tao, F Liu, R Zeng, PA Champagne, Y Cao, KN Houk, ... Chemical Communications 54 (100), 14089-14092, 2018 | 44 | 2018 |
In situ activation of benzyl alcohols with XtalFluor-E: formation of 1, 1-diarylmethanes and 1, 1, 1-triarylmethanes through Friedel–Crafts benzylation J Desroches, PA Champagne, Y Benhassine, JF Paquin Organic & biomolecular chemistry 13 (8), 2243-2246, 2015 | 42 | 2015 |
Faster initiation in the Friedel-Crafts reaction of benzyl fluorides using trifluoroacetic acid as activator R Hemelaere, PA Champagne, J Desroches, JF Paquin Journal of Fluorine Chemistry 190, 1-6, 2016 | 39 | 2016 |
Stereocontrolled Access to Unsymmetrical 1, 1-Diaryl-2-fluoroethenes G Landelle, MO Turcotte-Savard, J Marterer, PA Champagne, JF Paquin Organic letters 11 (23), 5406-5409, 2009 | 36 | 2009 |
Triol-promoted activation of C–F bonds: Amination of benzylic fluorides under highly concentrated conditions mediated by 1, 1, 1-tris (hydroxymethyl) propane PA Champagne, A Saint-Martin, M Drouin, JF Paquin Beilstein journal of organic chemistry 9 (1), 2451-2456, 2013 | 35 | 2013 |
Influence of Endo-and Exocyclic Heteroatoms on Stabilities and 1, 3-Dipolar Cycloaddition Reactivities of Mesoionic Azomethine Ylides and Imines PA Champagne, KN Houk The Journal of Organic Chemistry 82 (20), 10980-10988, 2017 | 30 | 2017 |
Heterohelicenes through 1, 3-Dipolar Cycloaddition of Sydnones with Arynes: Synthesis, Origins of Selectivity, and Application to pH-Triggered Chiroptical Switch with CPL Sign … E Yen-Pon, F Buttard, L Frédéric, P Thuéry, F Taran, G Pieters, ... JACS Au 1 (6), 807-818, 2021 | 29 | 2021 |
Revised mechanistic explanation for the alcohol-promoted amination of benzylic fluorides under highly concentrated conditions: Computational and experimental evidence on a … PA Champagne, M Drouin, CY Legault, C Audubert, JF Paquin Journal of Fluorine Chemistry 171, 113-119, 2015 | 29 | 2015 |
Photoinitiated anti‐Hydropentafluorosulfanylation of Terminal Alkynes M Birepinte, PA Champagne, JF Paquin Angewandte Chemie International Edition 61 (1), e202112575, 2022 | 25 | 2022 |
Understanding and Interrupting the Fischer Azaindolization Reaction BJ Simmons, M Hoffmann, PA Champagne, E Picazo, K Yamakawa, ... Journal of the American Chemical Society 139 (42), 14833-14836, 2017 | 24 | 2017 |