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Alexander Q. Cusumano
Alexander Q. Cusumano
PhD Candidate, Stoltz Group, California Institute of Technology
Verified email at caltech.edu
Title
Cited by
Cited by
Year
Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)–C …
AQ Cusumano, BM Stoltz, WA Goddard III
Journal of the American Chemical Society 142 (32), 13917-13933, 2020
402020
Multireference description of nickel–aryl homolytic bond dissociation processes in photoredox catalysis
DA Cagan, GD Stroscio, AQ Cusumano, RG Hadt
The Journal of Physical Chemistry A 124 (48), 9915-9922, 2020
252020
Ir-catalyzed asymmetric allylic alkylation of dialkyl malonates enabling the construction of enantioenriched all-carbon quaternary centers
FA Moghadam, EF Hicks, ZP Sercel, AQ Cusumano, MD Bartberger, ...
Journal of the American Chemical Society 144 (18), 7983-7987, 2022
222022
Direct access to highly functionalized heterocycles through the condensation of cyclic imines and α-oxoesters
AQ Cusumano, MW Boudreau, JG Pierce
The Journal of organic chemistry 82 (24), 13714-13721, 2017
182017
3-Hydroxy-1, 5-dihydro-2H-pyrrol-2-ones as novel antibacterial scaffolds against methicillin-resistant Staphylococcus aureus
AQ Cusumano, JG Pierce
Bioorganic & medicinal chemistry letters 28 (16), 2732-2735, 2018
172018
Global Diastereoconvergence in the Ireland–Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids
TJ Fulton, AQ Cusumano, EJ Alexy, YE Du, H Zhang, KN Houk, BM Stoltz
Journal of the American Chemical Society 142 (52), 21938-21947, 2020
162020
The transition metal catalyzed [π2s+ π2s+ σ2s+ σ2s] pericyclic reaction: Woodward–Hoffmann rules, aromaticity, and electron flow
AQ Cusumano, WA Goddard III, BM Stoltz
Journal of the American Chemical Society 142 (45), 19033-19039, 2020
132020
Probing trends in enantioinduction via substrate design: Palladium-catalyzed decarboxylative allylic alkylation of α-enaminones
DC Duquette, AQ Cusumano, L Lefoulon, JT Moore, BM Stoltz
Organic letters 22 (13), 4966-4969, 2020
112020
Identifying the Imperative Role of Metal–Olefin Interactions in Catalytic C–O Reductive Elimination from Nickel (II)
TD Lohrey, AQ Cusumano, WA Goddard III, BM Stoltz
ACS catalysis 11 (16), 10208-10222, 2021
42021
Enantioselective 1, 3-Dipolar Cycloadditions of α-Methylene Lactams to Construct Spirocycles
Y Nishiura, KJ Gonzalez, AQ Cusumano, BM Stoltz
Organic Letters 25 (35), 6469-6473, 2023
32023
Investigations of an unexpected [2+ 2] photocycloaddition in the synthesis of (−)-scabrolide A from quantum mechanics calculations
T Zhang, AQ Cusumano, NJ Hafeman, SA Loskot, CE Reimann, SC Virgil, ...
The Journal of Organic Chemistry 87 (21), 14115-14124, 2022
32022
Synthetic strategy toward ineleganolide: A cautionary tale
AQ Cusumano, KN Houk, BM Stoltz
Tetrahedron 93, 132289, 2021
32021
Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α, β-Unsaturated Lactams: Enantioselective Construction of All-Carbon Quaternary Stereocenters in …
T Zhang, Y Nishiura, AQ Cusumano, BM Stoltz
Organic Letters 25 (35), 6479-6484, 2023
22023
Divergent Catalysis: Catalytic Asymmetric [4+ 2] Cycloaddition of Palladium Enolates
KN Flesch, AQ Cusumano, PJ Chen, CS Strong, SR Sardini, YE Du, ...
Journal of the American Chemical Society 145 (20), 11301-11310, 2023
22023
Origins of Enhanced Enantioselectivity in the Pd-Catalyzed Decarboxylative Allylic Alkylation of N-Benzoyl Lactams
AQ Cusumano, T Zhang, WA Goddard III, BM Stoltz
Catalysts 13 (9), 1258, 2023
12023
Molecular Dynamics Investigations of Dienolate [4+ 2] Reactions
PJ Chen, AQ Cusumano, KN Flesch, CS Strong, WA Goddard III, ...
Journal of the American Chemical Society, 2024
2024
Asymmetric Pericyclic Transformations from Reactive Palladium Intermediates
AQ Cusumano
California Institute of Technology, 2024
2024
Synthetic strategy toward ineleganolide: A cautionary tale.
B Stoltz, A Cusumano, K Houk
2021
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