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Trevor A. Hamlin FRSC
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Understanding chemical reactivity using the activation strain model
FMBTAH Pascal Vermeeren, Stephanie C. C. van der Lubbe, Célia Fonseca Guerra
Nature Protocols 15, 649-667, 2020
2002020
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent
TA Hamlin, M Swart, FM Bickelhaupt
ChemPhysChem 19 (11), 1315-1330, 2018
1802018
How Lewis Acids Catalyze Diels–Alder Reactions
P Vermeeren, TA Hamlin, I Fernández, FM Bickelhaupt
Angewandte Chemie 132 (15), 6260-6265, 2020
1392020
How dihalogens catalyze Michael addition reactions
TA Hamlin, I Fernández, FM Bickelhaupt
Angewandte Chemie International Edition 58 (26), 8922-8926, 2019
922019
Oxoammonium salt oxidations of alcohols in the presence of pyridine bases
JM Bobbitt, AL Bartelson, WF Bailey, TA Hamlin, CB Kelly
The Journal of Organic Chemistry 79 (3), 1055-1067, 2014
852014
Oxidation of α-Trifluoromethyl alcohols using a recyclable oxoammonium salt
CB Kelly, MA Mercadante, TA Hamlin, MH Fletcher, NE Leadbeater
The Journal of Organic Chemistry 77 (18), 8131-8141, 2012
802012
The Pauli repulsion-lowering concept in catalysis
TA Hamlin, FM Bickelhaupt, I Fernández
Accounts of Chemical Research 54 (8), 1972-1981, 2021
742021
Chemical reactivity from an activation strain perspective
P Vermeeren, TA Hamlin, FM Bickelhaupt
Chemical Communications 57 (48), 5880-5896, 2021
742021
PyFrag 2019—Automating the exploration and analysis of reaction mechanisms
X Sun, TM Soini, J Poater, TA Hamlin, FM Bickelhaupt
Journal of Computational Chemistry 40 (25), 2227-2233, 2019
732019
Role of orbital interactions and activation strain (distortion energies) on Reactivities in the normal and inverse electron-demand cycloadditions of strained and unstrained …
BJ Levandowski, TA Hamlin, FM Bickelhaupt, KN Houk
The Journal of organic chemistry 82 (16), 8668-8675, 2017
682017
Toward a unified mechanism for oxoammonium salt-mediated oxidation reactions: a theoretical and experimental study using a hydride transfer model
TA Hamlin, CB Kelly, JM Ovian, RJ Wiles, LJ Tilley, NE Leadbeater
The Journal of Organic Chemistry 80 (16), 8150-8167, 2015
662015
Nucleophilic substitution in solution: activation strain analysis of weak and strong solvent effects
TA Hamlin, B van Beek, LP Wolters, FM Bickelhaupt
Chemistry–A European Journal 24 (22), 5927-5938, 2018
602018
Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions
P Vermeeren, TA Hamlin, I Fernández, FM Bickelhaupt
Chemical Science 11 (31), 8105-8112, 2020
582020
Highly enantioselective organocatalytic Michael addition/cyclization cascade reaction of ylideneoxindoles with isothiocyanato oxindoles: A formal [3+ 2] cycloaddition approach …
F Tan, HG Cheng, B Feng, YQ Zou, SW Duan, JR Chen, WJ Xiao
European Journal of Organic Chemistry 2013 (11), 2071-2075, 2013
572013
Origin of the α‐Effect in SN2 Reactions
T Hansen, P Vermeeren, FM Bickelhaupt, TA Hamlin
Angewandte Chemie International Edition 60 (38), 20840-20848, 2021
552021
Structural distortion of cycloalkynes influences cycloaddition rates both by strain and interaction energies
TA Hamlin, BJ Levandowski, AK Narsaria, KN Houk, FM Bickelhaupt
Chemistry–A European Journal 25 (25), 6342-6348, 2019
532019
Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions
D Svatunek, N Houszka, TA Hamlin, FM Bickelhaupt, H Mikula
Chemistry–A European Journal 25 (3), 754-758, 2019
532019
Methylenation of perfluoroalkyl ketones using a Peterson olefination approach
TA Hamlin, CB Kelly, RM Cywar, NE Leadbeater
The Journal of Organic Chemistry 79 (3), 1145-1155, 2014
472014
A Unified Framework for Understanding Nucleophilicity and Protophilicity in the SN2/E2 Competition
P Vermeeren, T Hansen, P Jansen, M Swart, TA Hamlin, FM Bickelhaupt
Chemistry–A European Journal 26 (67), 15538-15548, 2020
422020
A continuous-flow approach to 3, 3, 3-trifluoromethylpropenes: bringing together Grignard addition, Peterson elimination, inline extraction, and solvent switching
TA Hamlin, GML Lazarus, CB Kelly, NE Leadbeater
Organic Process Research & Development 18 (10), 1253-1258, 2014
422014
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