Model for the structural changes occurring at low temperatures in

O Blaschko, P Fratzl, R Klemencic - Physical Review B, 1981 - APS
O Blaschko, P Fratzl, R Klemencic
Physical Review B, 1981APS
A structural model for the short-range-ordered state in Pd D x, with 0.7< x<~ 0.78, observed
at low temperatures, is proposed. The model describes the complicated diffuse intensity
contours with" mixed" microdomains consisting of cells of the Ni n Mo type. A simple
distortion, ie, a relaxation of the D atoms towards vacant sites, is introduced in the" mixed"
microdomain and accounts for the measured intensity asymmetry. Furthermore, a
measurement of the intensities of the superlattice reflections in the long-range-ordered Ni 4 …
Abstract
A structural model for the short-range-ordered state in Pd D x, with 0.7< x<~ 0.78, observed at low temperatures, is proposed. The model describes the complicated diffuse intensity contours with" mixed" microdomains consisting of cells of the Ni n Mo type. A simple distortion, ie, a relaxation of the D atoms towards vacant sites, is introduced in the" mixed" microdomain and accounts for the measured intensity asymmetry. Furthermore, a measurement of the intensities of the superlattice reflections in the long-range-ordered Ni 4 Mo structure is presented, and its result is reproduced by calculation, when the same relaxation towards the vacancy, is assumed. Finally an important Debye-Waller factor for the superlattice reflections is found.
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