The Thermodynamic Properties of Pure Palladium and its Alloys with Hydrogen between 30 and 300° K.

P Mitacek, JG Aston - Journal of the American Chemical Society, 1963 - ACS Publications
P Mitacek, JG Aston
Journal of the American Chemical Society, 1963ACS Publications
The heat capacities of palladium and its alloys (H/Pd: 0.125, 0.25, 0.50 and 0.75) have been
determined between 30 K. and room temperature. Slow irreversible processes in the alloys
have been studied and a method developed to obtain activation energies from the resulting
warm drifts. The functional relation of the heat ca-pacities to the temperature together with
the energies of activation havebeen used to develop a detailed model for the structure of the
alloys.
The heat capacities of palladium and its alloys (H/Pd: 0.125, 0.25, 0.50 and 0.75) have been determined between 30 K. and room temperature. Slow irreversible processes in the alloys have been studied and a method developed to obtain activation energies from the resulting warm drifts. The functional relation of the heat ca-pacities to the temperature together with the energies of activation havebeen used to develop a detailed model for the structure of the alloys.
ACS Publications